Lecture 14: The Conservation of orbital symmetry (2 units)
5.7 分子轨道对称性守恒原理(Conservation of orbital symmetry)
5.7.1 前线轨道理论(Frontier orbitals theory)
5.7.2 相关图理论(Relevance graph theory)
Lecture 15: Rotational spectra (2 units)
6. 结构分析原理(The principles of structural analysis)
6.1 分子中的量子化能级(Quantized energy levels of molecules)
6.2 分子光谱(Molecular spectroscopy)
6.2.1 双原子分子的转动光谱(Rotational spectra of diatomic molecules)
(1) 转动惯量 (Moments of inertia)
(2) 转动能级(The rotational energy levels)
(3) 微波谱(Microwave spectra)
(4) 由微波谱计算键长(Calculation of bond length from Microwave spectra)
(5) 转动 Raman 光谱(Rotational Raman spectra)
(6) 由 Raman 光谱计算键长(Calculation of bond length from Raman spectra)
6.2.2 多原子分子的转动光谱(Rotational spectra of polyatomic molecules)
(1) 惯量椭球与主轴的选择(Ellipsoid of inertia and selection of principal axis)
(2) 刚性转子的类型(Types of Rigid Rotors)
(3) 各类陀螺的转动惯量(Moments of inertiab of various gyroscopes)
(4) 各类转子的能级和谱项(Energy levels and terms of various rotors)
Lecture 16: Vibrational spectra and Electronic spectra (2 units)
6.2.3 双原子分子振动光谱(Vibrational spectra of diatomic molecules )
(1) 谐振子的能级和波函数(The energy levels and the wavefunctions of harmonic oscillator)
(2) 谐振子的跃迁选律与振动光谱(Selection rules and vibrational spectra of harmonic oscillator)
(3) 非谐性的跃迁选律与振动光谱(Selection rules and vibrational spectra of anharmonic oscillator)
(4) 振-转红外光谱(Vibration–rotation Infrared absorption spectra)
(5) 振-转 Raman 光谱(Vibration–rotation Raman spectra)